Title of article
Preparation of diarylamines by the addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes
Author/Authors
Yang، نويسنده , , Tianle and Cho، نويسنده , , Bongsup P. Cho، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
7549
To page
7552
Abstract
The addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes in THF (−78°C) affords the corresponding diarylamines in one-pot and the reaction appears to be general in scope. A ‘nitroso’-based mechanism is proposed for this novel nitroreductive N-arylation reaction.
Keywords
Nitroarene , diarylamine , aryllithium
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1654890
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