• Title of article

    Conversion of alcohols to bromides using a fluorous phosphine

  • Author/Authors

    Desmaris، نويسنده , , Laurence and Percina، نويسنده , , Nathalie and Cottier، نويسنده , , Louis and Sinou، نويسنده , , Denis، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    3
  • From page
    7589
  • To page
    7591
  • Abstract
    Reaction of alcohols with the fluorous phosphinecarbon tetrabromide complex in toluene or in a two-phase toluene-FC-72 system afforded the corresponding bromides in good yields. The fluorous-phosphine oxide is readily separated by liquid–liquid extraction, providing an alternative to the homogeneous triphenylphosphine–carbon tetrachloride conversion, as well as to the polymer-supported phosphine method. The fluorous phosphine oxide could be reduced and the product reused.
  • Keywords
    fluorous triphenylphosphine , Tetrabromomethane , recycling , fluorous solvent
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1654911

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1654911