Title of article
Additive effects in palladium–indium mediated Barbier type allylations
Author/Authors
Cleghorn، نويسنده , , Laura A.T and Cooper، نويسنده , , Ian R and Grigg، نويسنده , , Ronald and MacLachlan، نويسنده , , William S and Sridharan، نويسنده , , Visuvanathar، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
5
From page
7969
To page
7973
Abstract
The effect of adding 1 equiv. of an amine or 0.2 equiv. of CuI to a Pd/In bimetallic cascade reaction is described. In the class 1 cascade reaction of aldehydes, aryl iodides and allene, generating homoallylic alcohols, the reaction time is reduced from 16 to 2 h and is accompanied by an impressive increase in yield.
Keywords
Barbier allylation , Additives , Indium
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1655171
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