Title of article
Synthesis of tetrahydrofurans via silicon promoted Pummerer type reaction
Author/Authors
Raghavan، نويسنده , , Sadagopan and Rajender، نويسنده , , Abdul Aziz A. Al-Rasheed، نويسنده , , M.Abdul and Reddy، نويسنده , , S.Ramakrishna، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
8253
To page
8256
Abstract
A novel, unprecedented transformation of δ-hydroxysulfoxides into substituted tetrahydrofurans by a silicon promoted Pummerer type reaction is disclosed. The transformation is shown to be general and is brought about under very mild reaction conditions. The products with the sulfide group at the anomeric carbon provide a suitable handle to carry out further transformations.
Keywords
Pummerer rearrangement , tetrahydrofurans , t-butyldiphenylchlorosilane , Sulfoxide
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1655369
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