Author/Authors :
Kerrigan، نويسنده , , Nessan J and Dunne، نويسنده , , Eoin C and Cunningham، نويسنده , , Desmond and McArdle، نويسنده , , Patrick and Gilligan، نويسنده , , Karen and Gilheany، نويسنده , , Declan G، نويسنده ,
Abstract :
Several routes to P-chirogenic binaphthyl monophosphanes (MOPs) and their derivatives were investigated. Palladium catalysed coupling gave access to a new class of P-chirogenic phosphane oxides from which the phosphane can be obtained by reduction. Substituents on phosphorus strongly influence the efficiency of the P–C coupling reaction, which is only slightly stereoselective.
