Title of article :
The first C2 selective halide substitution reaction of 2,3-epoxy alcohols by the use of (CH3O)3B–MX (X=I, Br, Cl) system
Author/Authors :
Tomata، نويسنده , , Yoshihide and Sasaki، نويسنده , , Minoru and Tanino، نويسنده , , Keiji and Miyashita، نويسنده , , Masaaki، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
The first C2 selective halide substitution reactions of 2,3-epoxy alcohols have been realized by the use of the (CH3O)3B–MX (X=I, Br, Cl) system, which proceed through novel endo-mode epoxide-opening of intramolecular boron chelates to afford the corresponding C2 halohydrin derivatives with high regio- and stereoselectivity.
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
