Title of article :
Synthesis of 2-alkylidene-cycloalkane-1,3-diols via enantioselective intramolecular carbolithiation
Author/Authors :
Gralla، نويسنده , , Gabriele and Wibbeling، نويسنده , , Birgit and Hoppe، نويسنده , , Dieter، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
The lithiodestannylation and intramolecular anti-selective carbolithiation of α-lithiated ω-carbamoyloxy-1-alkynyl carbamates have been used to synthesize highly enantioenriched protected 2-alkylidene-cycloalkane-1,3-diols.
Keywords :
chiral alkylidene-cyclobutanes and -cyclohexane , asymmetric deprotonation , (?)-sparteine , lithiodestannylation , intramolecular carbolithiation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
