Title of article :
A novel synthesis of α-hydroxy- and α,α′-dihydroxyketone from α-iodo and α,α′-diiodo ketone using photoirradiation
Author/Authors :
Horiuchi، نويسنده , , C.Akira and Takeda، نويسنده , , Akinori and Chai، نويسنده , , Wen and Ohwada، نويسنده , , Kishoh and Ji، نويسنده , , Shun-Jun and Takahashi، نويسنده , , T.Tomoyoshi، نويسنده ,
Abstract :
A novel reaction of α-iodo ketone (α-iodocycloalkanone, α-iodo-β-alkoxy ester, and α-iodoacyclicketone) with irradiation under a high-pressure mercury lamp gave the corresponding α-hydroxyketone in good yields. In the case of α,α′-diiodo ketone, α,α′-dihydroxyketone which little has been reported until now was obtained. This reaction affords a new, clean and convenient synthetic method for α-hydroxy- and α,α′-dihydroxyketone.
