Title of article
Asymmetric construction of quaternary carbon centers by titanium-mediated stereospecific allylation of 2,3-epoxy alcohol derivatives
Author/Authors
Ohno، نويسنده , , Hiroaki and Hiramatsu، نويسنده , , Kei and Tanaka، نويسنده , , Tetsuaki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
75
To page
78
Abstract
A general procedure for the asymmetric construction of a quaternary carbon center from readily available 2,3-epoxy alcohol derivatives was developed. Ring-opening reaction of 2-substituted 2,3-epoxy alcohol derivatives with a reagent prepared from allylmagnesium halide and chlorotitanium triphenoxide affords allylated 1,3-diols having a chiral quaternary carbon as a single isomer by the anti pathway.
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1656192
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