Title of article :
Enantioselective synthesis of the C-14 to C-5 cyclopentane segment of jatrophane diterpenes
Author/Authors :
Helmboldt، نويسنده , , Hannes and Rehbein، نويسنده , , Julia and Hiersemann، نويسنده , , Martin، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
The enantioselective synthesis of the C-14 to C-5 cyclopentane segment of jatrophane diterpenes is reported. An Evans aldol addition, a Horner–Wadsworth–Emmons olefination and a thermal intramolecular carbonyl ene reaction of an α-keto ester served as key C/C-connecting transformations.
Keywords :
Diterpene , Jatrophane , Euphorbia , Carbonyl ene reaction , total synthesis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
