Title of article :
Copper(I) tert-butoxide-promoted coupling of o-(1-hydroxyalkyl)arylsilanes with organic halides
Author/Authors :
Taguchi، نويسنده , , Haruhiko and Takami، نويسنده , , Kazuto and Tsubouchi، نويسنده , , C.Akira and Takeda، نويسنده , , Takeshi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Copper(I) tert-butoxide-promoted coupling of arylsilanes possessing a 1-hydroxyalkyl group at the o-position with organic halides proceeded to give disubstituted arenes. The results indicate that an intermediary arylcopper species is formed by aromatic Csp2-to-O silyl migration.
Keywords :
allylation , Alkylation , silyl migration , arylsilane , copper(I) tert-butoxide
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters