Author/Authors :
Gupta، نويسنده , , Priti and Vasudeva Naidu، نويسنده , , S. and Kumar، نويسنده , , Pradeep، نويسنده ,
Abstract :
An efficient enantioselective synthesis of (R)- and (S)-massoialactone has been achieved. The key steps are the hydrolytic kinetic resolution of a racemic epoxyheptane with (R,R)-(salen)–CoIIIOAc complex and ring-closing metathesis of homoallylic alcohol derived acrylate esters using Grubb’s catalyst.