Title of article
Activation of silylphosphines by diethyl azodicarboxylate: novel silylation of alcohols
Author/Authors
Hayashi، نويسنده , , Minoru and Matsuura، نويسنده , , Yutaka W. Watanabe، نويسنده , , Yutaka، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
1409
To page
1411
Abstract
A novel activation mode of silylphosphines and an application of that to silylation of alcohols were described. Silylphosphines were found to be instantly activated by means of DEAD and PPTS to form reactive silyl cation equivalents. By using the activated species, silylation of alcohols successfully proceeded under mild acidic condition.
Keywords
silyl ether , Silylphosphine , Silylation
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657092
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