Title of article
Ring opening of 2,3-epoxy phenyl ketones upon reaction with nitric oxide
Author/Authors
Liu، نويسنده , , Zhongquan and Li، نويسنده , , Rui and Yang، نويسنده , , Desuo and Wu، نويسنده , , LongMin He، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
2
From page
1565
To page
1566
Abstract
Epoxide rings of 2,3-epoxy phenyl ketones were cleaved by nitric oxide, affording regioselectively the C-3 ring-opened products, erythro-α-hydroxyl nitrates (2), in a highly syn-selective manner (isolated yield of the erythro products up to 91%). Products were identified by NMR, MS, and X-ray crystallography. The reaction is assumed to be initiated by NO2, unlike a nucleophilic attack.
Keywords
Nitric oxide , Ring open , epoxides
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657191
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