Title of article
Synthesis of 1,1-diarylethylenes from an α-stannyl β-silylstyrene
Author/Authors
Belema، نويسنده , , Makonen and Nguyen، نويسنده , , Van N. and Christopher Zusi، نويسنده , , F.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
5
From page
1693
To page
1697
Abstract
The synthesis of a family of 1,1-diarylethylenes from an α-stannyl β-silylstyrene through a combination of a Stille coupling and a protodesilylation reaction is described. This approach avoids the problematic cine-substitution, which is a well documented side reaction during the palladium-assisted elaboration of α-substituted vinylstannanes to 1,1-disubstituted ethylenes.
Keywords
1 , 1-Diarylethylene , cine-Substitution , Stille coupling , Protodesilylation
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657246
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