• Title of article

    Titanocene-catalyzed formation of allylsilanes from allyl ethers and chlorosilanes

  • Author/Authors

    Nii، نويسنده , , Shinsuke and Terao، نويسنده , , Jun and Kambe، نويسنده , , Nobuaki، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2004
  • Pages
    4
  • From page
    1699
  • To page
    1702
  • Abstract
    A new method for silylation of allyl ethers with chlorosilanes has been developed by the use of Cp2TiCl2 as a catalyst. This reaction proceeds efficiently at −20 °C in THF using nBuMgCl. A plausible reaction pathway via allyltitanocene intermediate was proposed.
  • Keywords
    Titanocene dichloride , allyl ether , Allylsilane , Grignard reagent , Chlorosilane
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2004
  • Journal title
    Tetrahedron Letters
  • Record number

    1657247