Title of article
Titanocene-catalyzed formation of allylsilanes from allyl ethers and chlorosilanes
Author/Authors
Nii، نويسنده , , Shinsuke and Terao، نويسنده , , Jun and Kambe، نويسنده , , Nobuaki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
1699
To page
1702
Abstract
A new method for silylation of allyl ethers with chlorosilanes has been developed by the use of Cp2TiCl2 as a catalyst. This reaction proceeds efficiently at −20 °C in THF using nBuMgCl. A plausible reaction pathway via allyltitanocene intermediate was proposed.
Keywords
Titanocene dichloride , allyl ether , Allylsilane , Grignard reagent , Chlorosilane
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657247
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