Title of article :
Synthesis of embellished bicyclo[2.2.2]octenones and a sigmatropic 1,2-acyl shift in an excited state: a novel and stereoselective route to (±)-hirsutic acid C and complicatic acid
Author/Authors :
Singh، نويسنده , , Vishwakarma and Tosh، نويسنده , , Dilip K. and Mobin، نويسنده , , Shaikh M.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Formal syntheses of hirsutic acid C and complicatic acid via cycloaddition of cyclohexa-2,4-dienone with methyl methacrylate and a triplet sensitized 1,2-acyl shift are described. The X-ray crystal structure of one of the key intermediates is also reported.
Keywords :
cycloaddition , 1 , Complicatic acid , oxa-di-?-methane rearrangement , Hirsutic acid , 2-Acyl shift
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
