Title of article
Cu(II)-catalyzed enantioselective aldol condensation between malonic acid hemithioesters and aldehydes
Author/Authors
Orlandi، نويسنده , , Simonetta and Benaglia، نويسنده , , Maurizio and Cozzi، نويسنده , , Franco، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
1747
To page
1749
Abstract
A mild, decarboxylative, aldol-type addition of malonic acid hemithioesters to aldehydes has been shown to occur with up to 39% enantioselectivity when the reaction was carried out in the presence of catalytic amounts of a Cu(II) salt, an enantiopure, tartaric acid-derived bis-benzimidazole and an achiral base.
Keywords
Malonic acid hemithioesters , Enantiopure benzimidazoles , Enantioselective catalysis , Aldol process
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657268
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