Title of article
A novel highly regio- and diastereoselective haloamination of alkenes catalyzed by divalent palladium
Author/Authors
Lei، نويسنده , , Aiwen and Lu، نويسنده , , Xiyan and Liu، نويسنده , , Guosheng، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
1785
To page
1788
Abstract
From the readily available allylic alcohols or allylic amines, a novel Pd(II)–CuCl2-catalyzed haloamination reaction of alkenes with high chemo-, regio-, and diastereo-selectivity was developed. The reaction proceeds through trans-aminopalladation of alkenes, followed by oxidative cleavage of the carbon–palladium bond with retention of configuration.
Keywords
Coupling reaction , ?-Heteroatom elimination , Carbopalladation , Divalent palladium
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657287
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