Title of article :
Silyl group deprotection by Pd/C/H2. A facile and selective method
Author/Authors :
Kim، نويسنده , , Seongjin and Marie Jacobo، نويسنده , , Sheila and Chang، نويسنده , , Chih-Tsung and Bellone، نويسنده , , Sophie and Powell، نويسنده , , William S. and Rokach، نويسنده , , Joshua، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
An easy, high yield, RT, short-reaction-time Pd/C hydrogenation of silyl groups is described. This includes TES, TPS, TBS, TBDMS, TIPS, and TBDPS. The relative selectivity of the process has been investigated and we can show, for example, that TES, TPS, TBS, and TBDMS removal can be performed in the presence of TIPS and TBDPS.
Keywords :
TES , TPS , TBS , TBDPS , tBDMS , Hydrogenolysis , TIPS
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
