Title of article
Co(III) porphyrin/DMAP: an efficient catalyst system for the synthesis of cyclic carbonates from CO2 and epoxides
Author/Authors
Paddock، نويسنده , , Robert L. and Hiyama، نويسنده , , Yaeko and McKay، نويسنده , , Jonathan M. and Nguyen، نويسنده , , SonBinh T. Nguyen، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
2023
To page
2026
Abstract
CoTPP(Cl)/DMAP was found to be a highly active catalyst system for the chemical fixation of CO2 via reaction with epoxides. The corresponding cyclic carbonate products are produced in high yield and selectivity for a variety of terminal mono and disubstituted epoxides. 1,2-Disubstituted internal epoxides were also investigated as substrates and found to react with very high stereospecificity.
Keywords
Cyclic carbonates , Co(III) porphyrin , CO2 fixation , epoxides
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657400
Link To Document