Title of article
Conjugate reduction of aryl acrylates with tributyltin hydride in the presence of magnesium bromide diethyl etherate
Author/Authors
Hirasawa، نويسنده , , Satomi and Nagano، نويسنده , , Hajime and Kameda، نويسنده , , Yoko، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
2207
To page
2209
Abstract
The conjugate reduction of aryl acrylates performed with tributyltin hydride in the presence of magnesium bromide diethyl etherate in dichloromethane gave the corresponding saturated esters in moderate to high yields. The reduction of α-methylene-γ-benzyloxycarboxylic acid esters proceeded syn-selectively, but α-methylene-β-oxycarboxylic acid esters afforded reductive elimination products under the reaction conditions.
Keywords
Aryl acrylate , Conjugate reduction , tributyltin hydride , Lewis acid
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657499
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