Author/Authors :
Haino، نويسنده , , Takeharu and Nakamura، نويسنده , , Masaki and Kato، نويسنده , , Nobuki and Hiraoka، نويسنده , , Miki and Fukazawa، نويسنده , , Yoshimasa، نويسنده ,
Abstract :
Shape-selective recognition for the dicarboxylates in DMSO can be attained by a new calix[4]arene-based receptor 1 having two urea groups. Biologically active chorismate selectively bound in 1 over its dehydrated derivative. Molecular mechanics calculations gave a plausible explanation for the selective binding.
Keywords :
Supramolecular chemistry , Host–guest chemistry , Hydrogen bonding , Molecular mechanics