Title of article
The design of molecules containing planar tetracoordinate carbon
Author/Authors
Priyakumar، نويسنده , , U.Deva and Reddy، نويسنده , , A.Srinivas and Sastry، نويسنده , , G.Narahari، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
2495
To page
2498
Abstract
A novel preference for planar tetracoordination was observed over the conventional tetrahedral arrangement in a new series of C5H2, C5H4, C5H41+/2+ and related compounds. The stability of these molecules is assessed with the ring-opening barriers, HOMO–LUMO gap, singlet–triplet energy differences and nucleus independent chemical shift values.
Keywords
Planar tetracoordinate carbon , Singlet–triplet gap , Ring-opening barrier , Nucleus independent chemical shift , Aromatic stabilization
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657640
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