Author/Authors :
Khan، نويسنده , , Tahir and Skabara، نويسنده , , Peter J. and Frère، نويسنده , , Pierre and Allain، نويسنده , , Magali and Coles، نويسنده , , Simon J. and Hursthouse، نويسنده , , Michael B.، نويسنده ,
Abstract :
We report the synthesis, crystal structures and redox chemistry of two new TTF derivatives bearing fused triaryl units. Both compounds show significant planarisation within conjugated regions, assisted by close intramolecular S⋯O contacts. The extended-TTF analogue displays multi-redox activity and can be oxidised sequentially to the tetracation species.
Keywords :
Synthesis , X-ray crystallography , tetrathiafulvalene , Electrochemistry
