Title of article
Boron trifluoride-catalyzed reaction of alkyl fluoride with silyl enolate, allylsilane, and hydrosilane
Author/Authors
Hirano، نويسنده , , Koji and Fujita، نويسنده , , Kazuya and Yorimitsu، نويسنده , , Hideki and Shinokubo، نويسنده , , Hiroshi and Oshima، نويسنده , , Koichiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
2555
To page
2557
Abstract
Alkylation of silyl enolates with tert-alkyl or allylic fluorides proceeds smoothly in the presence of a catalytic amount of boron trifluoride to afford the corresponding carbonyl compounds. Allylation and reduction of alkyl fluorides with allylsilane and hydrosilane, respectively, occur under BF3 catalysis.
Keywords
Alkyl fluoride , Alkylation , Silyl enolate , Boron trifluoride , silane
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657665
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