Reinvestigation of the reaction between sodium diethyl phosphite and diethyl phosphorochloridate. Evidence for a SET process in the formation of a direct P(IV)P(IV) bond
Author/Authors :
Kinas، نويسنده , , Ryszard W and Okruszek، نويسنده , , Andrzej and Stec، نويسنده , , Wojciech J، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Pages :
5
From page :
7875
To page :
7879
Abstract :
Alkali metal salts of diethyl phosphites act as nucleophiles or electron donors in reactions with diethyl phosphorochloridate. Evidence is provided that formation of the direct P(IV)P(IV) bond proceeds via a single electron transfer process (SET) from phosphite anion to phosphorochloridate.
