Title of article
Synthesis of the first homobimetallic thiazole–ferrocene ligand displaying metal–metal interaction and redox-switchable proton affinity
Author/Authors
L. L. Tàrraga، نويسنده , , Alberto and Molina، نويسنده , , Pedro and Curiel، نويسنده , , David and Velasco، نويسنده , , Ma? Desamparados، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
5
From page
8453
To page
8457
Abstract
The previously unreported 2,5-bis(ferrocenyl)thiazole 4, prepared from α-aminoacetylferrocene and chlorocarbonylferrocene in two steps, exhibits two reversible redox processes, indicating a significant electronic interaction between the iron centres. Electrochemical investigation of the protonated ligand revealed a reversible electrochemically-driven deprotonation/reprotonation process.
Keywords
Electrochemistry , Protonation , Ferrocenes , thiazoles
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1659080
Link To Document