Title of article
Facile route to dihydroindacene type ligands using multiple Heck reactions on aryl polybromides
Author/Authors
Ceccon، نويسنده , , Alberto and Crociani، نويسنده , , Laura and Santi، نويسنده , , Saverio and Venzo، نويسنده , , Alfonso and Biffis، نويسنده , , Andrea and Boccaletti، نويسنده , , Giovanni، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
8475
To page
8478
Abstract
The Heck reaction of aryl dibromides and n-butyl acrylate catalyzed by Pd(OAc)2/P(t-Bu)3 is a high yielding method to produce intermediates for dihydroindacene type ligands. The same synthetic strategy, extended to tribromides, represents a simple route also to tridentate ligands potentially useful in the stabilization of trimeric metal complexes and clusters.
Keywords
ligand molecules , Heck reaction , PALLADIUM , Catalysis , functionalized benzenes
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1659095
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