Author/Authors :
Prashad، نويسنده , , Mahavir and Liu، نويسنده , , Yugang and Mak، نويسنده , , Xiao Yin and Har، نويسنده , , Denis and Repi?، نويسنده , , Oljan and Blacklock، نويسنده , , Thomas J.، نويسنده ,
Abstract :
An inter- followed by an intramolecular double Heck reaction of bridged o,o′-dibromobiaryls with ethyl acrylate is described. The nature of the bridging atom/group determined the outcome of the reaction. This double Heck reaction strategy afforded a safe and convenient synthesis of 9-(ethoxycarbonylmethylene)-9H-xanthene and a novel route to 9 and/or 10-substituted anthracene derivatives.
