Title of article
Heterolytic decarboxylation involving acyltrifluoroacetyl peroxide intermediates
Author/Authors
Krasutsky، نويسنده , , Pavel A. and Kolomitsyn، نويسنده , , Igor V. and Botov، نويسنده , , Evgenij M. and Carlson، نويسنده , , Robert M. and Semenova، نويسنده , , Irina G. and Fokin، نويسنده , , Andrey A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
5
From page
8687
To page
8691
Abstract
Selective carboxylic acid decarboxylation was elaborated. Generation of acyltrifluoroacetyl peroxides from carboxylic peracids and trifluoroacetyl anhydride (Method A), as well as from trifluoroperacetic acid and acyltrifluoroacetyl anhydride (Method B), leads to simultaneous peroxide decomposition into the corresponding alkyltrifluoroacetates. DFT computations, as well as experimental data, support an acid-catalyzed heterolytic mechanism for acyltrifluoroacetyl peroxide decomposition.
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1659216
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