Author/Authors :
Yokota، نويسنده , , Takahiro and Sakakura، نويسنده , , Aki and Tani، نويسنده , , Masayuki and Sakaguchi، نويسنده , , Satoshi and Ishii، نويسنده , , Yasutaka، نويسنده ,
Abstract :
Selective Wacker-type oxidation of long-chain terminal alkenes to methylketones was successfully achieved by using Pd(OAc)2/molybdovanadophosphate (NPMoV)/O2 system. The selectivity of the reaction increased by slow addition of the alkenes to the catalytic solution. The oxidation of α,ω-dienes was also examined, and the selectivity of the oxidation was found to depend on the chain length of the dienes used.
