Title of article :
Synthesis and odor of optically active rose oxide
Author/Authors :
Yamamoto، نويسنده , , Takeshi and Matsuda، نويسنده , , Hiroyuki and Utsumi، نويسنده , , Yasuhide and Hagiwara، نويسنده , , Toshimitsu and Kanisawa، نويسنده , , Tsuneyoshi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Stereoselective synthesis of optically active rose oxide (1) by KHSO4 and Pd–BINAP-catalyzed cyclization of (3R)- and (3S)-3,7-dimethyl-6,7-octadien-1-ol (5) is described. One-pot synthesis of the (3R)- and (3S)-allenyl alcohol 5 from (3R)- and (3S)-citronellol (2) (98% ee) is also described. Furthermore, the odor properties of the four diastereomers of 1 are reported.
Keywords :
Rose oxide , Diastereomer , cyclization , (3R)- and (3S)-citronellol , (3R)- and (3S)-3 , 7-dimethyl-5 , 6-octadien-1-ol , Pd–(R)- and (S)-BINAP complexes , Odor
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
