Title of article :
The Heck reaction in the presence of molecular oxygen
Author/Authors :
Hosokawa، نويسنده , , Takahiro and Kamiike، نويسنده , , Taisuke and Murahashi، نويسنده , , Shun-Ichi and Shimada، نويسنده , , Mamoru and Sugafuji، نويسنده , , Toshihiro، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Palladium-catalyzed reaction of CH2C(R)COOMe (R=H or CH2OH) with PhI in the presence of NEt3 under O2 induces the oxidative dealkylation of NEt3, affording either methyl 3-diethylaminopropionate (3) or methyl (Z)-2-benzyl-3-(N,N′-diethylamino)propenate (6), in case of R=H or R=CH2OH, respectively.
Keywords :
Oxidation , Oxygen , PALLADIUM , amination , Heck reaction
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
