The mechanism of the tertiary amine catalysed isomerisation of endoperoxides to hydroxyketones: synthesis and chemistry of the intermediate postulated in the peroxide attack mechanism
Author/Authors :
Kelly، نويسنده , , David R. and Bansal، نويسنده , , Harjinder and Morgan، نويسنده , , J.J.Gwynfor، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Pages :
3
From page :
9331
To page :
9333
Abstract :
Evidence is presented which demonstrates that the Kornblum–DeLaMare rearrangement does not proceed via nucleophilic attack of the peroxide linkage.
