Title of article
Cu(I)-catalyzed allylic amination of olefins
Author/Authors
Hogan، نويسنده , , Gregg A and Gallo، نويسنده , , August A and Nicholas، نويسنده , , Kenneth M and Srivastava، نويسنده , , Radhey S، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
9505
To page
9508
Abstract
The copper(I) complex [Cu(CH3CN)4]PF6 catalyzes the allylic amination of alkenes by aryl hydroxylamine in fair to moderate yields. Unsymmetrical alkenes react with high regioselectivity with N-functionalization occuring at the less substituted vinylic carbon. Trapping experiments indicate that free PhNO is not an intermediate in these reactions.
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1659686
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