• Title of article

    Dirhodium(II) tetrakis[N-tetrachlorophthaloyl-(S)-tert-leucinate]: a new chiral Rh(II) catalyst for enantioselective amidation of CH bonds

  • Author/Authors

    Yamawaki، نويسنده , , Minoru and Tsutsui، نويسنده , , Hideyuki and Kitagaki، نويسنده , , Shinji and Anada، نويسنده , , Masahiro and Hashimoto، نويسنده , , Shunichi، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    9561
  • To page
    9564
  • Abstract
    Dirhodium(II) tetrakis[N-tetrachlorophthaloyl-(S)-tert-leucinate], characterized by substitution of chlorine atoms for four hydrogen atoms on the phthalimido group in the parent dirhodium(II) complex has been found to be well suited for enantioselective amidation of benzylic CH bonds with [(4-nitrophenyl)sulfonylimino]phenyliodinane. The observed enantioselectivity of up to 84% ee is the highest reported to date for dirhodium(II) complex-catalyzed CH amidations.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1659715

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1659715