Unexpected reactivity of oxygenated 2-acyl-1,3-dithianes with electrophiles
Author/Authors :
Smietana، نويسنده , , Michael and Valleix، نويسنده , , Alain and Mioskowski، نويسنده , , Charles، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Pages :
4
From page :
213
To page :
216
Abstract :
Lithium enolates of oxygenated acyl-dithiane undergo unexpected regiospecific reactions with electrophiles. Reaction of aldehydes with oxygenated acyl-dithiane leads to the formation of the corresponding monosubstituted β-hydroxy-acyl-dithiane.