Title of article
Diastereo- and regioselective palladium–indium bimetallic cyclisation–Barbier-type allylation cascades
Author/Authors
Cooper، نويسنده , Paul W , Ian R. and Grigg، نويسنده , , Ronald and MacLachlan، نويسنده , , William S. and Sridharan، نويسنده , , Visuvanathar and Thornton-Pett، نويسنده , , Mark، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
3
From page
403
To page
405
Abstract
A new diastereo-and regioselective Pd/In bimetallic cascade process which assembles three contiguous chiral centres is described. Pd(0)-catalysed cyclisation of aryl iodides onto proximate 1,3-dienes generates π-allylpalladium(II) species, transmetallation with indium and subsequent Barbier-type addition to aldehydes affords heterocyclic homoallylic alcohols.
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660050
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