Title of article :
Strong π-electron donors based on a self-rigidified 2,2′-bi(3,4-ethylenedioxy)thiophene–tetrathiafulvalene hybrid π-conjugated system
Author/Authors :
Leriche، نويسنده , , Philippe and Turbiez، نويسنده , , Mathieu and Monroche، نويسنده , , Vincent and Frère، نويسنده , , Pierre and Blanchard، نويسنده , , Philippe and Skabara، نويسنده , , Peter J. and Roncali، نويسنده , , Jean، نويسنده ,
Abstract :
Strong π-donors based on the association of TTF and 2,2′-bi(3,4-ethylenedioxy)thiophene conjugating unit have been synthesised; optical and an X-ray data show that intramolecular interactions lead to full rigidification of the conjugated system.