Author/Authors :
Sato، نويسنده , , Itaru and Kadowaki، نويسنده , , Kousuke and Urabe، نويسنده , , Hiroki and Jung، نويسنده , , Jong Hwa and Ono، نويسنده , , Yoshiyuki and Shinkai، نويسنده , , Seiji and Soai، نويسنده , , Kenso، نويسنده ,
Abstract :
Highly enantiomerically enriched (up to 96–97% ee) 5-pyrimidyl alkanol was obtained by the addition of diisopropylzinc to pyrimidine-5-carbaldehyde in the presence of the artificially designed chiral inorganic material, right- and left-handed helical silica.
Keywords :
Asymmetric induction , asymmetric synthesis , Asymmetric autocatalysis , silica , addition reactions
