Rh(I)-catalyzed addition of alkenylzirconocene chlorides to aldimine derivatives

[RhCl(COD)]2 (2 mol%) catalyzed reactions of alkenylzirconocene chloride complexes to N-Ts, -PO(OEt)2 and COOR aldimine derivatives were efficiently carried out in dioxane at room temperature to give allylic amine derivatives in excellent yields. This is the first example of the catalytic addition reactions of alkenylzirconocene chloride complexes to aldimine derivatives.