Title of article :
Regioselective allylation reactions using crotyl Grignard reagent–CeCl3 systems
Author/Authors :
Matsukawa، نويسنده , , Satoru and Funabashi، نويسنده , , Yohei and Imamoto، نويسنده , , Tsuneo، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
Regioselective allylation reactions using crotyl Grignard reagent–CeCl3 systems are described. Regioselectivity depends on the lanthanide salts: α-product was predominantly produced with light rare earth elements such as La, Ce, Pr, Nd, whereas γ-product was formed when heavy rare earth elements were used.
Keywords :
regiocontrol , allylation , cerium and compounds , Grignard reagents
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters