Title of article :
Hydrogen generation from ethanol in supercritical water without catalyst
Author/Authors :
Arita، نويسنده , , Toshihiko and Nakahara، نويسنده , , Koichi and Nagami، نويسنده , , Kenzo and Kajimoto، نويسنده , , Okitsugu، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
Without oxidizing reagents or catalysts, ethanol was smoothly converted to CH3CHO and H2 in supercritical water at 450–500°C. CH3CHO was further decomposed into CH4 and CO instead of being oxidized into acetic acid. These features suggest the direct participation of water molecules in the ethanol dehydrogenation.
Keywords :
Ethanol , supercritical water , Dehydroxylation , Wall effect , decomposition , Oxidation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
