Title of article
Acid-catalyzed transformation of rubrene to indenonaphthacene and its paired interacting orbital (PIO) analysis
Author/Authors
Hosokawa، نويسنده , , Takahiro and Nakano، نويسنده , , Hiromi and Takami، نويسنده , , Kazuto and Kobiro، نويسنده , , Kazuya and Shiga، نويسنده , , Akinobu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
3
From page
1175
To page
1177
Abstract
Treatment of rubrene (5,6,11,12-tetraphenylnaphthacene) with trifluoroacetic acid in dichloromethane gives 4b,9,10-triphenyl-4b,9-dihydroindeno[1,2,3-fg]naphthacene (1) as the sole isolable product. Paired interacting orbital (PIO) analysis indicates that the reaction is initiated by preferential attack of H+ at C(11) position of rubrene.
Keywords
Rubrene , paired interacting orbitals , indenonaphthacene , Rearrangement
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660504
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