Title of article :
Acid-catalyzed transformation of rubrene to indenonaphthacene and its paired interacting orbital (PIO) analysis
Author/Authors :
Hosokawa، نويسنده , , Takahiro and Nakano، نويسنده , , Hiromi and Takami، نويسنده , , Kazuto and Kobiro، نويسنده , , Kazuya and Shiga، نويسنده , , Akinobu، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
Treatment of rubrene (5,6,11,12-tetraphenylnaphthacene) with trifluoroacetic acid in dichloromethane gives 4b,9,10-triphenyl-4b,9-dihydroindeno[1,2,3-fg]naphthacene (1) as the sole isolable product. Paired interacting orbital (PIO) analysis indicates that the reaction is initiated by preferential attack of H+ at C(11) position of rubrene.
Keywords :
Rubrene , paired interacting orbitals , indenonaphthacene , Rearrangement
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
