Author/Authors :
Trofimov، نويسنده , , Boris A and Malysheva، نويسنده , , Svetlana F and Sukhov، نويسنده , , Boris G and Belogorlova، نويسنده , , Natalʹya A and Schmidt، نويسنده , , Elena Yu and Sobenina، نويسنده , , Lyubov N and Kuimov، نويسنده , , Vladimir A. and Gusarova، نويسنده , , Nina K، نويسنده ,
Abstract :
Secondary phosphines 1–3 react readily with N-vinylpyrroles 4 and 5 under radical initiation to give regiospecifically anti-Markovnikov adducts, diorganyl-2-(1-pyrrolyl)ethylphosphines 6a–d, highly reactive building blocks for organic synthesis, in 88–91% yields.
Keywords :
Radical initiation , functional tertiary phosphines , secondary phosphines , N-vinylpyrroles , Addition