Title of article :
A remarkably simple α-oximation of ketones to 1,2-dione monooximes using the chlorotrimethylsilane–isoamyl nitrite combination
Author/Authors :
Mohammed، نويسنده , , Abdulkarim H.A and Nagendrappa، نويسنده , , Gopalpur، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
Ketones undergo α-oximation by NOCl formed in situ from Me3SiCl and isoamyl nitrite, either in solution or under solvent-free conditions, to produce 1,2-dione monooximes in excellent yields. The oximation is regiospecific in appropriate cases.
Keywords :
Oximation , amyl nitrite , TMSCl , 1 , 2-diketone monooxime , NOCl
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
