Author/Authors :
Capperucci، نويسنده , , Antonella and DeglʹInnocenti، نويسنده , , Alessandro and Biondi، نويسنده , , Simona and Nocentini، نويسنده , , Tiziano and Rinaudo، نويسنده , , Giuseppe، نويسنده ,
Abstract :
Treatment of different silylated allenes with hexamethyldisilathiane (HMDST) in the presence of CoCl2·6H2O affords an easy and high yielding access to α,β-unsaturated thioacylsilanes, which undergo a self-dimerization reaction to afford polyfunctionalized 1,2-dithiins as the major products.
