Author/Authors :
Gurjar، نويسنده , , Mukund K. and Nagaprasad، نويسنده , , Ravi and Ramana، نويسنده , , C.V.، نويسنده ,
Abstract :
A total synthesis of the natural product microcarpalide is described. Ring-closing metathesis of a dienic ester was used as the key step. Mannose was used as the chiral pool material for the construction of the olefinic-acid and a Sharpless asymmetric dihydroxylation reaction provided the chiral precursor for the synthesis of the olefinic-alcohol.
