Title of article
Trienylboronic acid, a versatile coupling tool for retinoid synthesis; stereospecific synthesis of 13-aryl substituted (11Z)-retinal
Author/Authors
Uenishi، نويسنده , , Junʹichi and Matsui، نويسنده , , Katsuaki and Wada، نويسنده , , Akimori، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
3093
To page
3096
Abstract
Trienylboronic acid 1a was prepared from iodotriene 3, which was coupled with (2Z,4Z)-3-aryl-5-iodo-2,4-pentadienol 9 by Suzuki coupling reaction to give geometrically pure 13-aryl substituted (11Z)-retinol 10. Oxidation of 10 gave 13-aryl substituted (11Z)-retinal 11.
Keywords
conjugated pentaene , 11Z-retinal , iododiene , trienylboronic acid , Suzuki coupling
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1661651
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